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Photoluminescence: Fluorescence and Phosphorescence01:23

Photoluminescence: Fluorescence and Phosphorescence

Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
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Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...

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Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
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Published on: May 9, 2021

Segregation in water-based stable single-bubble sonoluminescence.

Mogens T Levinsen1

  • 1BioComplexity Lab, Niels Bohr Institute, University of Copenhagen, Blegdamsvej 17, DK-2100 Copenhagen Ø, Denmark. levinsen@nbi.dk

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|March 10, 2012
PubMed
Summary
This summary is machine-generated.

Investigating single-bubble sonoluminescence, this study found that gas mixtures in bubbles highly thermalize radiation, even without species segregation. This challenges previous theories about shock waves influencing sonoluminescence spectra.

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Area of Science:

  • Acoustics
  • Plasma Physics
  • Spectroscopy

Background:

  • Single-bubble sonoluminescence (SBSL) spectra closely resemble blackbody radiation, posing a long-standing question about the underlying physics.
  • The transparency of bubbles to their own radiation and the potential role of shock waves or compression waves have been debated.

Purpose of the Study:

  • To investigate the mechanism behind the thermalized spectra in single-bubble sonoluminescence.
  • To determine if species segregation within the bubble, indicative of shock waves, correlates with spectral characteristics.

Main Methods:

  • Experimental investigation of sonoluminescence spectra from bubbles seeded with gas mixtures (He/Ne with Xe/Ar).
  • Application of a specific spectral transformation for single-parameter characterization tailored to the experimental setup.

Main Results:

  • No evidence of species segregation was detected in the gas mixtures within the bubbles.
  • Despite the absence of segregation, the emitted radiation consistently exhibited highly thermalized characteristics across all tested gas mixtures.

Conclusions:

  • The findings suggest that species segregation is not a prerequisite for the observed thermalized radiation in single-bubble sonoluminescence.
  • The high degree of thermalization in SBSL spectra may arise from mechanisms other than shock-induced species segregation.