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Preparation of alkyl-modified silicon nanosheets by hydrosilylation of layered polysilane (Si6H6)

Hideyuki Nakano1, Mitsuru Nakano, Koji Nakanishi

  • 1Toyota Central R&D Laboratories, Inc, Nagakute, Aichi, Japan. hnakano@mosk.tytlabs.co.jp

Journal of the American Chemical Society
|March 15, 2012
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.