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Unexpected electronic properties of micrometer-thick supracrystals of Au nanocrystals
Peng Yang1, Imad Arfaoui, Tristan Cren
1Laboratoire des Matériaux Mésoscopiques et Nanométriques (LM2N), UMR CNRS 7070, Université Pierre et Marie Curie (UPMC), bât F, BP 52, 4 place Jussieu, 75252 Paris Cedex 05, France.
Abstract:
We investigated the electronic properties of highly ordered three-dimensional colloidal crystals of gold nanocrystals (7 ± 0.4 nm), called supracrystals. Two kinds of Au supracrystals with typical thicknesses of 300 nm and 5 μm, respectively, are probed for the first time with scanning tunneling microscopy/spectroscopy at 5 K revealing similar power law behavior and showing homogeneous conductance with the fingerprint of isolated nanocrystal. Potential applications evading the size-related risks of nanocrystals could be then considered.

