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Published on: February 4, 2013
Facile synthesis of concave decahedra enclosed by high-index facets and truncated decahedra with a large size
Lin-Fei Zhang1, Lei Wang, Sheng-Liang Zhong
1Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
Abstract:
Nanostructures with concave surfaces are not common, and their synthesis is still challenging. In this paper, we have successfully synthesized two kinds of five-fold-twinned Au decahedra and dodecagonal plates by changing the reaction conditions. 40 high-index {221} facets were observed in the concave decahedron. The truncated decahedral gold nanocrystals (NCs) with a large size of 250-350 nm were obtained for the first time, which breaks the assumption that the truncated five-fold-twinned Au nanoparticles (NPs) can only be obtained with a size below 5 nm. The growth mechanism and the evolution process of the gold nanostructures were discussed. This work provides a facile way to synthesize concave decahedra, truncated decahedra and dodecagonal plates with controlled nanostructures.
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