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Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
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Enhanced performance of the catalytic conversion of allyl alcohol to 3-hydroxypropionic acid using bimetallic gold

Ermelinda Falletta1, Cristina Della Pina, Michele Rossi

  • 1Dipartimento di Chimica Inorganica, Metallorganica e Analitica L. Malatesta, Università degli Studi di Milano, CNR-ISTM, via Venezian, 21, 20133 Milano, Italy.

Faraday Discussions
|March 30, 2012
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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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