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Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Published on: September 18, 2016

Advances in copper-catalyzed C-C coupling reactions and related domino reactions based on active methylene compounds

Yunyun Liu1, Jie-Ping Wan

  • 1College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China.

Chemistry, an Asian Journal
|April 5, 2012
PubMed

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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