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First evidence for the formation of technetium oxosulfide complexes: synthesis, structure and characterization

Maryline Ferrier1, Philippe F Weck, Frederic Poineau

  • 1Department of Chemistry, University of Nevada Las Vegas, Las Vegas, NV 89154, USA.

Dalton Transactions (Cambridge, England : 2003)
|April 13, 2012
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.