Related Experiment Video
Updated: May 23, 2026

Synthesis and Characterization of Amphiphilic Gold Nanoparticles
Published on: July 2, 2019
Bonding of gold with unsaturated species
Paola Nava1, Denis Hagebaum-Reignier, Stéphane Humbel
1Aix-Marseille Université, Institut des Sciences Moléculaires de Marseille iSm2-UMR-CNRS-7313, Campus St. Jérôme, service 561, 13397 Marseille cedex 20, France. paola.nava@univ-amu.fr
Abstract:
Interactions of gold(I) catalysts with alkenes and alkynes are analyzed. Neutral chlorido, and cationic phosphine and N-heterocyclic carbene complexes are studied. High-level ab initio calculations are performed to benchmark the accuracy of popular DFT methods. Donation and backdonation contributions in the bond between the gold fragment and the alkene/alkyne substrate are discussed. These contributions depend on the nature of the gold fragment, but also on the substituents on the alkene/alkyne.
More Related Videos
Related Concept Videos
Bonding in Metals
Immunogold Electron Microscopy
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Valence Bond Theory
Valence Bond Theory
Types of Chemical Bonds

