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Fullerene/cobalt porphyrin hybrid nanosheets with ambipolar charge transporting characteristics
Takatsugu Wakahara1, Pasquale D'Angelo, Kun'ichi Miyazawa
1Fullerene Engineering Group, Advanced Materials Processing Unit, Advanced Key Technologies Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. Wakahara.takatsugu@nims.go.jp
Abstract:
A novel supramolecular nanoarchitecture, comprising C(60)/Co porphyrin nanosheets, was prepared by a simple liquid-liquid interfacial precipitation method and fully characterized by means of optical microscopy, AFM, STEM, TEM, and XRD. It is established that the highly crystalline C(60)/Co porphyrin nanosheets have a simple (1:1) stoichiometry, and when incorporated in bottom-gate, bottom-contact field-effect transistors (FETs), they show ambipolar charge transport characteristics.
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