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Cross-linked multifunctional conjugated polymers prepared by in situ electrochemical deposition for a

Cheng Gu1, Wenyue Dong, Liang Yao

  • 1State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Qianjin Avenue, Changchun, P. R. China.

Advanced Materials (Deerfield Beach, Fla.)
|April 21, 2012
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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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