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Coating Pt(0) nanoparticles with methyl groups: the reaction between methyl radicals and Pt(0)-NPs suspended in

Ronen Bar-Ziv1, Israel Zilbermann, Tomer Zidki

  • 1Nuclear Research Centre Negev and Chemistry Dept. Ben-Gurion University of the Negev, Beer-Sheva, Israel.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|April 26, 2012
PubMed
Abstract

No abstract available in PubMed .

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Methylation is a phase II biotransformation process involving the attachment of a methyl group to a substrate. Enzymes known as methyltransferases orchestrate this reaction.
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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.

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