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Morphology Control for Fully Printable Organic–Inorganic Bulk-heterojunction Solar Cells Based on a Ti-alkoxide and Semiconducting Polymer
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Versatile chromism of titanium oxide hydrate/poly(vinyl alcohol) hybrid systems

Manuela Russo1, Stephen E J Rigby, Walter Caseri

  • 1Department of Materials, Eidgenössische Technische Hochschule-ETH, Zürich, CH-8093 Zürich, Switzerland.

Advanced Materials (Deerfield Beach, Fla.)
|May 3, 2012
PubMed
Abstract

No abstract available in PubMed .

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Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction01:22

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.