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Preparation, chemical and electrical characterizations of lipid nanoparticles loaded with dihydroxybenzophenone

Jesús Hierrezuelo1, Juana Benavente, Juan Manuel López-Romero

  • 1Dep. Química Orgánica, Facultad de Ciencias, Universidad de Málaga, E-29071 Málaga, Spain.

Medicinal Chemistry (Shariqah (United Arab Emirates))
|May 11, 2012
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Simple aryl halides do not react with nucleophiles under normal conditions. However, the reaction can proceed under drastic conditions involving high temperatures and high pressure to give the substituted products. For example, chlorobenzene is converted to phenol using aqueous sodium hydroxide at 350 °C under high pressure by the Dow process. The reaction follows an elimination-addition mechanism involving a benzyne intermediate. Here, the chloride ion is eliminated to generate the benzyne...