Related Experiment Video
Updated: May 22, 2026

Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
(2,9-Dimethyl-1,10-phenanthroline-κ(2)N,N')bis-(2-meth-oxy-benzoato-κ(2)O(1),O(1'))cadmium
1College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, People's Republic of China.
Abstract:
In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-meth-oxy-benzoate anions in a distorted octa-hedral environment. Two O atoms of one bidentate 2-meth-oxy-benzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π-π stacking inter-actions between the dmphen rings of neighboring mol-ecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å.
More Related Videos
05:21The Effect of Ultraviolet Radiation on the Chemical Bath Deposition of Bis(thiourea) Cadmium Chloride Crystals and the Subsequent CdS Obtention
Published on: August 30, 2018
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Related Concept Videos
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
EDTA: Chemistry and Properties
Coordination Compounds and Nomenclature
Valence Bond Theory
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Coordination Number and Geometry