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![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
{5,5'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}palladium(II)
Abstract:
In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol-ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd-O and Pd-N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21 (4)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the ab plane. These planes are further connected by C-H⋯O inter-actions, forming a three-dimensional network.

