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Updated: May 22, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
catena-Poly[[(p-toluene-sulfonato-κO)silver(I)]-μ-1,3-bis-(pyridin-4-yl)propane-κ(2)N:N']
Feng Ma1, Dai-Bao Wei, Zhi-Min Cao
1Shandong Polytechnic University, School of Chemistry and Pharmaceutical Engineering, Jinan 250353, People's Republic of China.
Abstract:
In the title compound, [Ag(C(7)H(7)O(3)S)(C(13)H(14)N(2))](n), the Ag(I) ion is coordinated in a T-shape by two N atoms from two symmetry-related 1,3-bis-(pyridin-4-yl)propane ligands and one O atom from a p-toluene-sulfonate ligand, forming a one-dimensional zigzag chain along [001]. In the crystal, weak C-H⋯O hydrogen bonds and weak Ag⋯Ag inter-actions [3.2628 (5) Å] are observed.
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