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Updated: May 22, 2026

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
(Acetato-κO)(2-bromo-6-{[3-(dimethyl-aza-nium-yl)propyl-imino-κN]meth-yl}phenolato-κO)(thio-cyanato-κN)zinc
1College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, People's Republic of China.
Abstract:
In the title compound, [Zn(CH(3)COO)(NCS)(C(12)H(17)BrN(2)O)], the Zn(II) atom is four-coordinated in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of an acetate ligand and one thio-cyanate N atom. In the crystal, mol-ecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers.
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