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Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Dichloridobis[2-(1-hydrazinylideneeth-yl)pyrazine-κN(1)]zinc
Li-Li Liang1, Meng Li, Jia-Cheng Liu
1College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China.
Abstract:
In the structure of the title complex, [ZnCl(2)(C(6)H(8)N(4))(2)], the Zn(II) atom has a distorted octa-hedral geometry. Two cis Cl(-) ions and four N atoms belonging to two different 2-(1-hydrazinylideneeth-yl)pyrazine ligands coordinate the Zn(II) atom, forming two five-membered Zn-N-C-C-N rings. The dihedral angle between the planes of these metallocycles is 88.13 (4)°. The organic ligands are essentially planar (r.m.s. deviations from planarity = 0.072 and 0.040 Å). Inter-molecular N-H⋯N and N-H⋯Cl inter-actions join the mol-ecules into a three-dimensional framework.
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