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Updated: May 22, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
11-(4-Meth-oxy-phen-yl)-3,3-dimethyl-2,3,4,5,10,11-hexa-hydro-1H-dibenzo[b,e][1,4]diazepin-1-one monohydrate
Abstract:
In the title compound, C(22)H(24)N(2)O(2)·H(2)O, the co-crystallized water mol-ecule inter-acts with the N and O atoms of the mol-ecule through O(w)-H⋯N, O(w)-H⋯O(meth-yl) and N-H⋯O(w) hydrogen-bonding inter-actions. These hydrogen bonds, along with the inter-molecular N-H⋯O=C hydrogen-bonding inter-actions, connect the mol-ecules into a three-dimensional network. The dihedral angle between the two aromatic rings is 65.46 (10)°.
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