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Updated: May 22, 2026
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09:12
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Bis(4-meth-oxy-pyridin-3-yl)diazene
Summary
This study details the molecular structure of a novel organic compound, C(12)H(12)N(4)O(2). The research reveals a unique step-like molecular shape with a trans-configured azo group and parallel pyridine rings.
Area of Science:
- Crystallography
- Organic Chemistry
- Molecular Structure
Background:
- Understanding the precise three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties and reactivity.
- The study of heterocyclic compounds, such as those containing pyridine rings, is a significant area in organic chemistry due to their diverse applications.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(12)H(12)N(4)O(2).
- To characterize the molecular geometry, including the configuration of the azo group and the relative orientation of the pyridine rings.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed to determine the molecular and crystal structure.
- The asymmetric unit was analyzed, revealing the presence of a center of inversion.
Main Results:
- The asymmetric unit contains one half-molecule, situated on a crystallographic center of inversion.
- The molecule exhibits a distinct step-like conformation.
- The azo group (-N=N-) was confirmed to be in a trans configuration.
- The pyridine rings were observed to be arranged in a parallel-displaced orientation.
Conclusions:
- The detailed structural analysis provides fundamental insights into the solid-state behavior of this specific organic compound.
- The observed molecular geometry, including the trans azo group and parallel pyridine rings, may influence the compound's chemical and physical properties.
- This structural data serves as a basis for further investigations into related compounds and their potential applications.
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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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In the Sandmeyer reaction, for example, the diazonio group is replaced by a chloro, bromo, or cyano...
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