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Catalytic activity of halohydrin dehalogenases towards spiroepoxides

Maja Majerić Elenkov1, Ines Primožič, Tomica Hrenar

  • 1Ruđer Bošković Institute, Bijenička c. 54, 10000 Zagreb, Croatia. majeric@irb.hr

Organic & Biomolecular Chemistry
|May 25, 2012
PubMed

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Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of peroxy acids to...
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