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Updated: May 21, 2026
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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
Published on: February 10, 2023
Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies
Maxim N Sokolov1, Sergey A Adonin, Pavel A Abramov
1Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Prosp. Lavrentieva 3, Novosibirsk, Russia. caesar@niic.nsc.ru
Chemical Communications (Cambridge, England)
|May 30, 2012
Abstract:
A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na(12)[(Rh(4)(μ(3)-O)(2)(H(2)O)(2))(H(2)W(9)O(33))(2)]·38H(2)O (1) was obtained by hydrothermal reaction of rhodium(II) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by (183)W NMR data; 1 is active in electrocatalytic water oxidation.
