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Drift velocity in non-isothermal inhomogeneous systems
Mingcheng Yang1, Marisol Ripoll
1Theoretical Soft-Matter and Biophysics, Institute of Complex Systems, Forschungszentrum Jülich, 52425 Jülich, Germany. m.yang@fz-juelich.de
In inhomogeneous suspensions, drift velocity and driving force aren't directly proportional. Particle flux also depends on self-diffusion gradients, challenging existing approximations in mass transport.
Area of Science:
- Physics
- Physical Chemistry
- Materials Science
Background:
- Inhomogeneous suspensions exhibit complex transport phenomena.
- Traditional models often assume direct proportionality between drift velocity and driving force, which may not hold true.
Purpose of the Study:
- To investigate the relationship between drift velocity, driving force, and particle flux in inhomogeneous suspensions.
- To explore the influence of space-dependent mobility and self-diffusion gradients on mass transport.
- To validate simulation findings against theoretical approximations.
Main Methods:
- Computer simulations of a non-equilibrium system.
- Inclusion of a temperature gradient to induce mass transport.
- Analysis of space-dependent mobility and self-diffusion coefficients.
Main Results:
- Drift velocity is not directly proportional to the driving force in inhomogeneous suspensions due to space-dependent mobility.
- Particle flux is influenced by both density and self-diffusion coefficient gradients.
- The thermal diffusion coefficient is not directly proportional to drift velocity, indicating approximations in current theories.
Conclusions:
- The direct proportionality between drift velocity and driving force is an approximation for inhomogeneous systems.
- Self-diffusion gradients play a crucial role in particle flux.
- Simulation results highlight the limitations of simplified models in describing complex mass transport phenomena.
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