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Voltammetry: Stripping Methods

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Anodic Stripping Voltammetry (ASV), Cathodic Stripping Voltammetry (CSV), and Adsorptive Stripping Voltammetry (AdSV) are electrochemical techniques used to determine trace amounts of analytes in solution. These methods involve applying a potential to an electrode and measuring the resulting current.
Anodic Stripping Voltammetry (ASV)
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Voltammetry: Overview

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Related Experiment Video

Updated: May 21, 2026

Electrochemical Preparation of Poly(3,4-Ethylenedioxythiophene) Layers on Gold Microelectrodes for Uric Acid-Sensing Applications

Electrochemical Preparation of Poly(3,4-Ethylenedioxythiophene) Layers on Gold Microelectrodes for Uric Acid-Sensing Applications

Published on: July 28, 2021

Proton transfer voltammetry at electrodes modified with acid thiol monolayers.

Antonio M Luque¹, Willem H Mulder, Juan José Calvente

¹Departamento de Química Física, Universidad de Sevilla , 41012-Sevilla, Spain.

Analytical Chemistry

|June 7, 2012

Summary

Proton transfer voltammograms are simplified by modeling electrode potential and activation energy. Narrow peaks indicate acid groups must be near the electrode surface for efficient proton transfer.

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Electrochemical Roughening of Thin-Film Platinum Macro and Microelectrodes

Electrochemical Roughening of Thin-Film Platinum Macro and Microelectrodes

Published on: June 30, 2019

Related Experiment Videos

Last Updated: May 21, 2026

Electrochemical Preparation of Poly(3,4-Ethylenedioxythiophene) Layers on Gold Microelectrodes for Uric Acid-Sensing Applications

Electrochemical Preparation of Poly(3,4-Ethylenedioxythiophene) Layers on Gold Microelectrodes for Uric Acid-Sensing Applications

Published on: July 28, 2021

Electrochemical Roughening of Thin-Film Platinum Macro and Microelectrodes

Electrochemical Roughening of Thin-Film Platinum Macro and Microelectrodes

Published on: June 30, 2019

Area of Science:

Electrochemistry
Surface Science
Physical Chemistry

Background:

Proton transfer at electrode surfaces is crucial for electrochemical reactions.
Understanding the factors influencing proton transfer kinetics is essential for designing efficient electrochemical systems.
Acid thiol monolayers on electrodes offer a model system to study interfacial proton transfer.

Purpose of the Study:

To derive a simplified expression for proton transfer voltammograms.
To investigate the influence of electrode potential and the location of acid groups on proton transfer.
To quantitatively analyze experimental voltammograms for insights into proton transfer mechanisms.

Main Methods:

Theoretical modeling combining electrode potential profiles with activation energy relationships.
Electrostatic analysis of proton transfer dynamics.
Quantitative fitting of experimental voltammograms using an Au(111) electrode modified with 11-mercaptoundecanoic acid.

Main Results:

A simple expression for proton transfer voltammograms was derived.
Proton transfer produces narrow voltammetric peaks only when acid groups are close to the metal substrate.
Less than 1% of carboxylic groups participated in potential-induced proton transfer, residing near the surface.

Conclusions:

The proximity of acid groups to the electrode surface is critical for narrow voltammetric peaks.
Interfacial electric fields can facilitate proton exchange even between non-contacting species.
Further kinetic analysis is needed to fully elucidate the proton transfer mechanism at interfaces.