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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...

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Synthesis of Hydrogels with Antifouling Properties As Membranes for Water Purification
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Sulfonated polybenzophenone/poly(arylene ether) block copolymer membranes for fuel cell applications.

Takahiro Miyahara1, Tetsuji Hayano, Soichi Matsuno

  • 1Frontier Materials Development Laboratories, Kaneka Corporation , 5-1-1 Torikai-nishi, Settu, Osaka 566-0072, Japan, and.

ACS Applied Materials & Interfaces
|June 14, 2012
PubMed
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New sulfonated polybenzophenone/poly(arylene ether) block copolymers offer superior proton conductivity and fuel cell performance. These advanced membranes demonstrate enhanced durability compared to current state-of-the-art proton conducting membranes.

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Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Electrochemistry

Background:

  • Proton exchange membranes are critical for fuel cell efficiency.
  • Nafion, a leading material, faces challenges in performance and durability.
  • Developing alternative membranes with improved properties is essential.

Purpose of the Study:

  • To design and synthesize novel sulfonated polybenzophenone/poly(arylene ether) block copolymers.
  • To evaluate their potential as advanced proton conducting membranes for fuel cells.
  • To compare their performance against Nafion.

Main Methods:

  • Synthesis via Nickel-mediated coupling polymerization.
  • Characterization of high-molecular-weight block copolymers with low polydispersity.
  • Fabrication and testing of membrane fuel cell performance.

Main Results:

  • Achieved high molecular weights (Mn = 70-110 kDa) and low polydispersity (Mw/Mn = 2.0-2.3).
  • Demonstrated well-developed phase separation, high proton conductivity, and low gas permeability.
  • Exhibited superior fuel cell performance and durability compared to Nafion membranes.

Conclusions:

  • Sulfonated polybenzophenone/poly(arylene ether) block copolymers represent a promising alternative to Nafion.
  • These novel materials offer enhanced fuel cell performance and durability.
  • The developed synthesis route yields high-quality block copolymers suitable for membrane applications.