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Related Concept Videos

Network Covalent Solids02:18

Network Covalent Solids

Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...

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Preparation of Graphene Liquid Cells for the Observation of Lithium-ion Battery Material
10:53

Preparation of Graphene Liquid Cells for the Observation of Lithium-ion Battery Material

Published on: February 5, 2019

Supramolecular ionic liquid based on graphene oxide.

Chunfang Zeng1, Zhenghai Tang, Baochun Guo

  • 1Department of Polymer Materials and Engineering, South China University of Technology, Guangzhou 510640, China.

Physical Chemistry Chemical Physics : PCCP
|June 19, 2012
PubMed
Summary
This summary is machine-generated.

Researchers created a novel liquefied graphene oxide (GO) supramolecular ionic liquid (SIL). This new GO-SIL fluid demonstrates excellent solubility and viscoelastic properties for advanced composite materials.

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Fabrication of Three-Dimensional Graphene-Based Polyhedrons via Origami-Like Self-Folding
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Scalable Syntheses of Graphene Oxide and Reduced Graphene Oxide using Cascade Design Oxidation and Highly Basic Reduction Reactions
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Fabrication of Three-Dimensional Graphene-Based Polyhedrons via Origami-Like Self-Folding

Published on: September 23, 2018

Area of Science:

  • Materials Science
  • Nanotechnology
  • Supramolecular Chemistry

Background:

  • Graphene oxide (GO) is a versatile nanomaterial with potential applications in composites.
  • Developing liquid forms of GO is crucial for easier processing and integration into materials.

Purpose of the Study:

  • To prepare a liquefied form of graphene oxide (GO).
  • To create a supramolecular ionic liquid (SIL) using GO.
  • To investigate the properties and potential applications of the resulting GO-based SIL.

Main Methods:

  • Sulfonation of GO using sodium sulfanilic acid.
  • Ionization of sulfonated GO with amine-terminated Jeffamine® to form a SIL.
  • Characterization of the GO-SIL's morphology, solubility, amphiphilicity, and rheological behavior.

Main Results:

  • Successfully synthesized a graphene oxide-based supramolecular ionic liquid (GO-SIL).
  • The GO-SIL exhibited excellent solubility and amphiphilicity.
  • Rheological measurements confirmed the viscoelastic and liquid-like nature of the GO-SIL.

Conclusions:

  • The developed GO-SIL is a promising material for fabricating graphene-based composite materials.
  • The functionalization method allows for tunable properties by modifying the Jeffamine® component.
  • This work opens avenues for novel graphene derivatives with tailored characteristics.