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All-metal layer-by-layer films: bimetallic alternate layers with accessible mesopores for enhanced electrocatalysis
Hongjing Wang1, Shinsuke Ishihara, Katsuhiko Ariga
1World Premier International Research Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
Abstract:
We have prepared multilayer mesoporous bimetallic (Pt/Pd) alternating films by layer-by-layer (LbL) electrochemical deposition. Because of the high surface area and heterometallic interfacial atomic contacts, enhanced electrocatalytic activity for methanol oxidation reaction is realized. This novel LbL approach allows optimization of the electrocatalytic performance through precise tuning of the thickness of each layer.
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