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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
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Dielectric-constant-enhanced hall mobility in complex oxides.

Wolter Siemons1, Michael A McGuire, Valentino R Cooper

  • 1Oak Ridge National Laboratory, Materials Science and Technology Division, Oak Ridge, Tennessee 37831, USA. siemonsw@ornl.gov

Advanced Materials (Deerfield Beach, Fla.)
|June 22, 2012
PubMed
Summary

Doped ferroelectric potassium tantalate niobate (KTa(1-x)Nb(x)O(3)) exhibits a high dielectric constant. This property enhances electron mobility by improving dielectric screening, overcoming a key limitation in functional oxide applications.

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Area of Science:

  • Materials Science
  • Solid State Physics
  • Oxide Electronics

Background:

  • Functional oxides are crucial in electronics, but their application is limited by electron scattering.
  • Ferroelectric materials offer unique dielectric properties that could potentially mitigate these limitations.

Purpose of the Study:

  • To investigate the effect of high dielectric constant in doped ferroelectric KTa(1-x)Nb(x)O(3) on electron mobility.
  • To determine if enhanced dielectric screening can overcome limitations in functional oxide applications.

Main Methods:

  • Transport measurements
  • Optical measurements
  • Band structure calculations

Main Results:

  • The high dielectric constant of doped KTa(1-x)Nb(x)O(3) effectively screens electron scatterers.
  • Enhanced dielectric screening leads to improved electronic mobility in these materials.

Conclusions:

  • Doped ferroelectric KTa(1-x)Nb(x)O(3) presents a promising pathway for overcoming electron scattering limitations in functional oxides.
  • The observed enhancement in electronic mobility opens new avenues for advanced oxide electronics.