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Updated: May 21, 2026
![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
[4-(Dimethyl-amino)-pyridine-κN(1)]tri-methyl(thio-cyanato-κN)tin(IV)
Abstract:
In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.
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