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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
1,4-Dimethyl-piperazine-1,4-diium dibromide dihydrate
1College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
Abstract:
In the title hydrated mol-ecular salt, C(6)H(16)N(2) (2+)·2Br(-)·2H(2)O, the complete 1,4-dimethyl-piperazine-1,4-diium dication is generated by crystallographic inversion symmetry and both exocyclic C-N bonds are in equatorial orientations. In the crystal, the components are linked by N-H⋯O and O-H⋯Br hydrogen bonds, generating chains propagating in [110].
