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dl-Alaninium iodide.

Kevin Lamberts1, Ulli Englert

  • 1Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

Acta Crystallographica. Section E, Structure Reports Online
|June 22, 2012
PubMed
Summary
This summary is machine-generated.

The crystal structure of dl-alanine hydro-iodide reveals homochiral helices formed by hydrogen-bonded cations. Iodide anions link these chains, creating a 2D network in the ab plane.

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Area of Science:

  • Crystallography
  • Solid-state chemistry
  • Organic chemistry

Background:

  • dl-alanine hydro-iodide is an organic salt composed of N-protonated cations and iodide anions.
  • Understanding the crystal structure is crucial for predicting material properties.

Purpose of the Study:

  • To determine the detailed crystal structure of dl-alanine hydro-iodide.
  • To elucidate the intermolecular interactions and network formation within the crystal.

Main Methods:

  • Single-crystal X-ray diffraction was employed to analyze the crystal structure.
  • Analysis of hydrogen bonding and crystallographic symmetry was performed.

Main Results:

  • The crystal structure consists of homochiral helices of N-protonated dl-alanine cations aligned along the [010] direction.
  • Iodide anions act as hydrogen bond acceptors, linking the helical chains into a two-dimensional network in the ab plane.
  • Neighboring chains exhibit opposite chirality due to crystallographic inversion centers.

Conclusions:

  • The study provides a detailed description of the dl-alanine hydro-iodide crystal structure.
  • The identified 2D network highlights the role of hydrogen bonding and anion interactions in organizing organic salts.