Wavelength-scale lens microscopy via thermal reshaping of colloidal particles

Lenses are by far the most simple tools for visualization. Although they are intrinsically limited in resolution, recent efforts have aimed at focusing visible light in micro-scale lenses with subwavelength resolution, triggering an intense interest in further improving and understanding their performances. Herein, we report on a distinctive library of wavelength-scale solid immersion lenses facilitated the self-assembly of polystyrene colloidal particles. The thermally activated structural changes in polystyrene colloidal spheres directly impact the optical performance of the obtained lenses. Similar melting dynamics is observed for spheres of various size spheres at different temperatures. This allows precise control of the contact angle spanning a broad range from 180° to <20°. The fabricated lenses display deviations from the ray optics, allowing us to resolve features as small as 180 nm using a simple microscopy setup. We succeed in proper self-assembly of the colloidal lenses that enables large-area optical nanoscopy through simple and reliable experimental protocols. The limitations and the artifacts of the present technique are discussed.