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Measuring the Densities of Aqueous Glasses at Cryogenic Temperatures
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Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks

Giulia Lorusso1, Maria A Palacios, Gary S Nichol

  • 1Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Departamento de Física de la Materia Condensada, 50009 Zaragoza, Spain.

Chemical Communications (Cambridge, England)
|June 26, 2012
PubMed

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...