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Updated: May 20, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Dependence of chaotic diffusion on the size and position of holes
Georgie Knight1, Orestis Georgiou, Carl P Dettmann
1School of Mathematical Sciences, Queen Mary University of London, Mile End Road, London E1 4NS, United Kingdom. g.knight@qmul.ac.uk
Abstract:
A particle driven by deterministic chaos and moving in a spatially extended environment can exhibit normal diffusion, with its mean square displacement growing proportional to the time. Here, we consider the dependence of the diffusion coefficient on the size and the position of areas of phase space linking spatial regions ('holes') in a class of simple one-dimensional, periodically lifted maps. The parameter dependent diffusion coefficient can be obtained analytically via a Taylor-Green-Kubo formula in terms of a functional recursion relation. We find that the diffusion coefficient varies non-monotonically with the size of a hole and its position, which implies that a diffusion coefficient can increase by making the hole smaller. We derive analytic formulas for small holes in terms of periodic orbits covered by the holes. The asymptotic regimes that we observe show deviations from the standard stochastic random walk approximation. The escape rate of the corresponding open system is also calculated. The resulting parameter dependencies are compared with the ones for the diffusion coefficient and explained in terms of periodic orbits.
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