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Updated: May 20, 2026

Laboratory Production of Biofuels and Biochemicals from a Rapeseed Oil through Catalytic Cracking Conversion
Published on: September 2, 2016
Distillate-range products from non-oil-based sources by catalytic cascade reactions
Antoine Lacarriere1, Julien Robin, Dariusz Swierczyński
1Institut Charles Gerhardt, UMR 5253 UM2-ENSCM-UMI-CNRS, 8, rue de l'Ecole Normale, 34296 Montpellier, France.
Abstract:
An original two-step process efficiently catalyzed by functionalized mesoporous materials is proposed as a potential route for converting light olefins into long-chain hydrocarbons in the distillate range. In the first step, ethylene can be selectively transformed into C₄ -C₁₀ olefins with an even number of carbon atoms, over nickel-exchanged AlMCM-41, at 150 °C. When the nickel-catalyzed oligomerization was assisted by a second acid-catalyzed step over H-MCM-41, olefins with chains longer than 10 carbon atoms were mainly produced with a productivity of 180 g g⁻¹ h⁻¹.
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