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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
A copper(II)-ethylenediamine modified polyoxoniobate with photocatalytic H2 evolution activity under visible light
Zhen-Li Wang1, Hua-Qiao Tan, Wei-Lin Chen
1Department of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024, China.
Dalton Transactions (Cambridge, England : 2003)
|July 6, 2012
Abstract:
A new dimer polyoxoniobate [Cu(en)(2)](11)K(4)Na(2)[KNb(24)O(72)H(9)](2)·120H(2)O (1) has been synthesized and systematically characterized. Visible light photocatalytic H(2) evolution activity was researched with 1 as the visible-light photosensitizer and catalyst, cobaloximes [Co(III)(dmgH)(2)pyCl] as the co-catalysts, and triethylamine (TEA) as the sacrificial electron donor.
