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Updated: May 20, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
08:25

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Published on: January 17, 2020

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Claire Besson1, Sebastian Schmitz, Kimberly M Capella

  • 1Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany.

Dalton Transactions (Cambridge, England : 2003)
|July 12, 2012
PubMed
Summary

A quantitative cycloaddition reaction within a {Mo(132)}-type Keplerate yields a 2:1 ratio of 1,4- and 1,5-triazoles from propiolic acid and azide guests. This demonstrates controlled synthesis of triazole isomers inside a molecular cage.

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