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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
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Terminal phosphinidene formation via tantalaziridine complexes

Matthew A Rankin1, Christopher C Cummins

  • 1Department of Chemistry, Massachusetts Institute of Technology, Room 6-435, 77 Massachusetts Avenue, Cambridge, MA 02139-4307, USA.

Dalton Transactions (Cambridge, England : 2003)
|July 14, 2012
PubMed
Summary

Bulky anilide ligands support the preparation of terminal, 4-coordinate phosphinidenes of tantalum (Ta). This synthesis involves metallaziridine phosphanide complexes in a novel reaction sequence.

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