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Updated: May 20, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via
Emmanuel Nicolas1, Xavier-Frédéric le Goff, Stéphane Bouchonnet
1Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, Ecole Polytechnique, 91128 Palaiseau Cedex, France.
Abstract:
Room temperature reversible C-H activation mediated by a designed diphosphine platinum complex is presented. These findings are demonstrated through mechanistic studies involving kinetics, isotopic effects, and corroborated by DFT calculations. The coupling between two unactivated aromatic derivatives is also demonstrated.
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