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Updated: May 20, 2026

Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells
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Diimidazolium phthalate monohydrate.

Chua-Hua Yu1

  • 1Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online
|July 17, 2012
PubMed
Summary
This summary is machine-generated.

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The crystal structure of a novel compound reveals a 3D network formed by hydrogen bonds. This network connects cations, anions, and water molecules through N-H⋯O and O-H⋯O interactions.

Area of Science:

  • Crystallography
  • Supramolecular Chemistry

Background:

  • Hydrogen bonding plays a crucial role in the self-assembly of crystal structures.
  • Understanding the network formation in crystalline solids is essential for materials science.

Purpose of the Study:

  • To elucidate the crystal structure of the title compound.
  • To investigate the hydrogen bonding interactions and network formation within the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
  • Analysis of hydrogen bonding geometry (N-H⋯O and O-H⋯O) was performed.

Main Results:

  • The crystal structure of 2C(3)H(5)N(2) (+)·C(8)H(4)O(4) (2-)·H(2)O was successfully determined.

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  • A three-dimensional network was observed, facilitated by extensive N-H⋯O and O-H⋯O hydrogen bonds.

    • Conclusions:

    • The hydrogen bonding interactions dictate the formation of a robust 3D supramolecular network in the title compound.
    • The study provides insights into the structural characteristics and intermolecular forces governing this crystalline material.