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Updated: May 20, 2026
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
1-(2-Chloro-benz-yl)-3-methyl-2,6-diphenyl-piperidine
Abstract:
In the title compound, C(25)H(26)ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chloro-benzene ring and the flanking phenyl rings are 74.91 (18) and 47.86 (17)°. The chloro substituent is anti to the piperidine N atom. In the crystal, centrosymmetrically related mol-ecules aggregate via π-π inter-actions occurring between chloro-benzene rings [centroid-centroid distance = 3.778 (2) Å] and these are linked into linear supra-molecular chains along the a axis by C-H⋯π inter-actions occurring between the phenyl rings.
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