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Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]-copper(II) perchlorate mono-hydrate
Baoyun Zhong1, Shengli Li, Guifang Chen
1The Third Middle School in Liaocheng, Shandong 252059, People’s Republic of China.
Abstract:
In the title compound, [Cu(C₇H₇N₂O)(C₇H₈N₂O)(H₂O)]ClO₄·H₂O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan-one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic ligands are linked by an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules and ions are linked by O-H⋯O hydrogen-bonding inter-actions, forming chains along the a axis. The perchlorate O atoms are disordered in a 0.58 (2):0.42 (2) ratio.
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