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Updated: May 20, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Di-μ-adipato-κ⁴O¹:O⁶-bis-{aqua-[5,6-di-phenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ²N²,N³]copper(II)}
1Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo 315211, People's Republic of China. xuwei@nbu.edu.cn
Abstract:
In the centrosymmetric binuclear title complex, [Cu₂(C₆H₈O₄)₂(C₂₀H₁₄N₄)₂(H₂O)₂] or [Cu₂(PDPT)₂(C₆H₈O₄)₂(H₂O)₂] (PDPT = 3-(2-pyrid-yl)-5,6-diphenyl-1,2,4-triazine, the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two PDPT N atoms and two O atoms from different adipate dianions while a water mol-ecule is located at the apical position. Of the two water H atoms, one participates in an intra-molecular hydrogen bond whereas the second participates in an inter-molecular hydrogen bond, which leads to the formation of a chain along [010].
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