Related Experiment Video
Updated: May 20, 2026

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
Published on: July 9, 2015
catena-Poly[[[diaqua-(1,10-phenan-thro-line)manganese]-μ-3-[3-(carboxyl-ato-meth-oxy)phen-yl]acrylato] monohydrate]
Jun Ji1, Yuan-Fa Yang, Yi-Hang Wen
1Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China.
Abstract:
The title compound, [Mn(C₁₁H₈O₅)(C₁₂H₈N₂)(H₂O)₂]·H₂O, was obtained under hydro-thermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN₂O₄ octa-hedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxyl-ate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Inter-molecular O-H⋯O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water mol-ecules are present.
Related Concept Videos
Anionic Chain-Growth Polymerization: Overview
Carboxylic Acids to Methylesters: Alkylation using Diazomethane
Anionic Chain-Growth Polymerization: Mechanism
Cationic Chain-Growth Polymerization: Mechanism
Characteristics and Nomenclature of Homopolymers
Ziegler–Natta Chain-Growth Polymerization: Overview

