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Updated: May 20, 2026

Investigations on the Ga(III) Complex of EOB-DTPA and Its 68Ga Radiolabeled Analogue
Published on: August 17, 2016
catena-Poly[[gallium(III)-bis-[μ-D/l-tartrato(2-)]-gallium(III)-di-μ-hydroxido] dihydrate]
Xiaojing Liu1, Ruijing Tian, Cailing Zhang
1Department of Materials and Chemical Engineering, Ministry of Education, Key Laboratory of Advanced Materials of Tropical Island Resources, Hainan University, Haikou 570228, People's Republic of China.
Abstract:
In the title compound, {[Ga(2)(C(4)H(4)O(6))(2)(OH)(2)]·2H(2)O}(n), the Ga(III) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from bridging hydroxide groups and four O atoms from two symmetry-related tartrate units in a slightly distorted octa-hedral environment. Each tartrate unit binds to two Ga(III) atoms as a bis-chelating bridging ligand by two pairs of hydroxide groups and an O atom of a carboxyl-ate group. The Ga(III) atoms are linked by two bridging hydroxide groups located on mirror planes. In this way a chain along the c axis is formed. Free water mol-ecules on mirror planes are located between the chains and hold them together through hydrogen-bonding inter-actions, with O⋯O distances in the range 2.509 (3)-3.179 (5) Å.
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