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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
1-Dichloro-acetyl-8a-methyl-1,2,3,4,6,7,8,8a-octa-hydro-pyrrolo-[1,2-a]pyrimidin-6-one
Shuang Gao1, Li-Xia Zhao, Fei Ye
1College of Science, Northeast Agricultural University, Harbin 150030, People's Republic of China.
Abstract:
In the title compound, C(10)H(14)Cl(2)N(2)O(2), the five-membered ring adopts an envelope conformation (with the methylene C atom closest to the C-N bridge as the flap), while the conformation of the six-membered ring is close to a twist-boat. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming chains along the c-axis direction.
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