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Related Concept Videos

Photoluminescence: Applications01:14

Photoluminescence: Applications

Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
Photoluminescence: Fluorescence and Phosphorescence01:23

Photoluminescence: Fluorescence and Phosphorescence

Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
Variables Affecting Phosphorescence and Fluorescence01:26

Variables Affecting Phosphorescence and Fluorescence

Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
Fluorescence and Phosphorescence: Instrumentation01:25

Fluorescence and Phosphorescence: Instrumentation

Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
Super-resolution Fluorescence Microscopy01:37

Super-resolution Fluorescence Microscopy

Super-resolution fluorescence microscopy (SRFM) provides a better resolution than conventional fluorescence microscopy by reducing the point spread function (PSF). PSF is the light intensity distribution from a point that causes it to appear blurred. Due to PSF, each fluorescing point appears bigger than its actual size, and it is the PSF interference of nearby fluorophores that causes the blurred image. Various approaches to achieving higher resolution through SRFM have recently been developed.

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Related Experiment Video

Updated: May 20, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
08:51

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Published on: October 24, 2017

From a fluorescent chromophore in solution to an efficient emitter in the solid state.

Yang Liu1, Yun Lv, Xiying Zhang

  • 1State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P. R. China.

Chemistry, an Asian Journal
|July 26, 2012
PubMed
Summary

Researchers developed a non-coplanar molecule from polycyclic aromatic hydrocarbons (PAHs) to achieve efficient solid-state fluorescence. This breakthrough enables highly luminescent materials for advanced applications like organic light-emitting diodes (OLEDs).

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Area of Science:

  • Materials Science
  • Organic Chemistry
  • Photophysics

Background:

  • Polycyclic aromatic hydrocarbons (PAHs) typically lose fluorescence in aggregated states due to π-π stacking.
  • The planar structure of PAHs enhances solution fluorescence but hinders solid-state emission.

Purpose of the Study:

  • To overcome fluorescence quenching in aggregated PAHs.
  • To develop efficient solid-state emitters for optoelectronic devices.

Main Methods:

  • Constructed a non-coplanar PAH-substituted ethene molecule.
  • Utilized fluoranthene as a planar building block.
  • Incorporated the molecule into organic light-emitting diodes (OLEDs).

Main Results:

  • Achieved a highly efficient solid-state emitter with unity fluorescence quantum efficiency in the aggregated state.
  • Demonstrated OLEDs with high luminance (20,520 cd/m²) and efficiency (10 cd/A).

Conclusions:

  • Non-coplanar molecular design effectively prevents PAH aggregation-caused quenching.
  • The developed material shows significant potential for high-performance solid-state lighting and displays.