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Chemical intercalation of zerovalent metals into 2D layered Bi2Se3 nanoribbons

Kristie J Koski1, Colin D Wessells, Bryan W Reed

  • 1Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, USA.

Journal of the American Chemical Society
|July 27, 2012
PubMed

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...