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Updated: May 20, 2026
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Targeted synthesis of a porous borazine-linked covalent organic framework
Karl T Jackson1, Thomas E Reich, Hani M El-Kaderi
1Department of Chemistry, Virginia Commonwealth University, Richmond, VA 23284-2006, USA.
Abstract:
The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (∼420 °C) and high porosity (SA(BET) = 1178 m(2) g(-1)) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol(-1).
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