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Enhanced fluoride adsorption using Al (III) modified calcium hydroxyapatite.

Yulun Nie1, Chun Hu, Chuipeng Kong

  • 1State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China.

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|July 31, 2012
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Aluminum-modified hydroxyapatite (Al-HAP) significantly enhances fluoride removal compared to unmodified hydroxyapatite (HAP). This Al-HAP material offers a more efficient and spontaneous adsorption process for defluoridation.

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Area of Science:

  • Materials Science
  • Environmental Chemistry
  • Adsorption Science

Background:

  • Hydroxyapatite (HAP) is a key material in various applications, but its defluoridation capacity can be limited.
  • Fluoride contamination in water poses significant health risks, necessitating effective removal strategies.

Purpose of the Study:

  • To synthesize and characterize aluminum-modified hydroxyapatite (Al-HAP).
  • To evaluate the defluoridation capacity and adsorption mechanism of Al-HAP for fluoride removal from aqueous solutions.

Main Methods:

  • X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) analyses for material characterization.
  • Batch adsorption experiments to determine defluoridation capacity (DC) and study the effects of pH, Al/Ca ratio, and co-existing anions.
  • Langmuir isotherm and pseudo-second-order kinetic models were applied to adsorption data.

Main Results:

  • Al-HAP exhibited a higher defluoridation capacity (32.57 mgF(-)/g) compared to HAP (16.38 mgF(-)/g).
  • Adsorption followed Langmuir isotherm and pseudo-second-order kinetics, indicating chemisorption.
  • Surface hydroxyl groups on Al-HAP act as adsorption sites, leading to enhanced fluoride removal efficiency.

Conclusions:

  • Aluminum modification significantly improves the defluoridation performance of hydroxyapatite.
  • Al-HAP is a promising adsorbent for efficient fluoride removal from water.
  • The adsorption process is spontaneous and endothermic, driven by surface hydroxyl groups.